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Frequently Asked Questions
What if I smell gas?
Do not touch electrical switches, light matches, or use the phone. Get everyone out of the building. Shut off the gas valve at the outside tank, meter, or service entrance. Call your propane gas supplier and/or the fire department from a neighbor’s phone.
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Is propane poisonous?
No. However, it is a simple asphyxiate. Which means that if one breathes propane vapor instead of air then suffocation may result.
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When I went in to get my grill cylinder filled they said I will need to have an OPD installed in my cylinder. What is an OPD?
OPD is an acronym meaning over-fill prevention device. Now required by national standards, an overfilling prevention device is a secondary means of assuring that cylinders are not overfilled. Overfilling of cylinders is a dangerous condition and has been determined to be the most frequent cause of propane cylinder accidents. As of October 1, 1998, all DOT cylinders with capacities of 4 pounds up to 40 pounds must be manufactured with an OPD-equipped valve. If your cylinder is inspected for re-qualification after October 1, 1998,
an OPD-equipped valve must be installed prior to the cylinder being refilled. As of April 1, 2002, cylinders without OPD’s cannot be refilled.
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How can I tell if my cylinder has an OPD-equipped valve?
OPD-equipped valves may be identified by: (1) a specially designed, triple-notched valve hand wheel and/or, (2) a hand wheel or valve body that is clearly marked with the letters OPD.
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Why should propane tanks and cylinders be painted a light color?
It is best to keep propane containers as cool as possible. Light reflective colors such as white or silver do not absorb heat from sunshine as readily as do darker colors thus keeping the tank cooler.
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Where should a non-portable propane tank or cylinder be installed?
As simple as this question sounds the answer can get very complicated. Rule of thumb is that if the tank is larger that 124 gallons water capacity (WC) then it should be placed no less than ten feet from just about everything. This includes your house or any building structure, property line, wood pile or other combustibles storage. Keep in mind that your propane service provider needs to be able to reach the tank with the delivery hose. Since most delivery hoses are 125 feet in length, the tank needs to be within 110 feet of a driveway or lane where the delivery truck may be parked safely and without getting stuck. Click here to view Container Spacing or Cylinders diagrams.
There are other considerations such as overhead power lines, the septic system, traffic protection and appearance (see Landscaping With Propane Tanks 101 in this web site).
If the tank capacity is 124 gallons WC or less and filled in place, it may be installed up next to the house or building provided there is no window, door, crawlspace opening within three feet of the filling connection on the tank AND provided there is no ventilation device, openings into direct-vent appliances, or any source of ignition within ten feet of the filling connection on the tank. This paragraph also applies to most cylinders filled in place. Click here to view Container Spacing or Cylinders diagrams.
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My regulator is “froze up”. What should I do?
First of all, call your propane service provider. They will need to know in order to prevent it from happening again. An immediate remedy, which you may perform yourself, is to warm up the regulator somehow. An electric blow dryer works well. Two quarts of hot tap water poured directly on the regulator will also do the trick. However, the regulator must be installed properly (vent pointed downward) in order for this to work. What ever you do, don’t use an open flame to thaw out the regulator.
If you see a frost or ice build up on the regulator or adjacent piping, do not be alarmed. This is normal and should not be confused with a typical regulator freeze up. A frosty or iced regulator is usually not a problematic condition with the propane system and may even be normal under certain climatic conditions.
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Why does propane have an odor?
Naturally, propane is odorless. Your supplier adds an “odorant” to the propane to permit the detection of leaks before gas concentrations reach a hazardous level. The odor is unpleasant so that the leak will be paid attention to and repaired.
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What is the difference between LP-gas and propane?
LP-gas is a general term referring to a family of chemical compounds known as hydrocarbons. Propane is one of these hydrocarbons and is therefore an LP-gas.
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What are some physical properties of propane?
| Formula |
C3H8 |
| Boiling Point, oF |
-44 |
| Specific Gravity of Liquid |
.51 |
| Specific Gravity of Vapor |
1.53 |
| Pounds per gallon of Liquid at 60oF |
4.24 |
| BTU per Gallon of Liquid at 60oF |
91,690 |
| BTU per pound of Liquid |
21,591 |
| BTU per Cubic Foot of Vapor at 60oF |
2,516 |
| Cubic Feet of Vapor at 60oF
per Gallon of Liquid at 60oF |
36.39 |
| Cubic Feet of Vapor at 60oF
per Pound of Liquid at 60oF |
8.547 |
| Latent Heat of Vaporization at
boiling Point (BTU per Gallon) |
785.0 |
| Cubic Feet of Air Required to Burn 1
Cubic Foot of Vapor |
23.86 |
| Flash Point, oF |
-156 |
| Ignition Temperature in Air, oF |
920-1120 |
| Maximum Flame Temperature in Air, oF |
3595 |
| Limits of Flammability, Percentage
of |
|
|
Vapor in Air Mixture: |
|
|
Lower Limit % |
2.4 |
|
Upper Limit |
9.6 |
| Octane Number (ISO-Octane =100) |
100+ |
When changing from a liquid to a vapor, propane will expand 270 times. One cubic foot of propane liquid will expand to 270 cubic feet of vapor.
Propane gas is heavier than air and will temporarily settle near the floor and in low lying areas such as crawl spaces and basements.
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What is a BTU?
BTU is an acronym for British Thermal Unit and is a heat value rating. By definition a BTU is the amount of heat required to increase the temperature of one pound of water one degree Fahrenheit.
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What BTU ratings would be found on typical domestic appliances?
| Kitchen range |
65,000 BTU |
| Built-n oven or broiler unit |
25,000 BTU |
| Built-n cooking top |
40,000 BTU |
| Water heater, 30 gallon |
35,000 BTU |
| Water heater, 50 gallon |
55,000 BTU |
| Clothes dryer |
35,000 BTU |
| Furnace for heating |
40,000 – 120,000 BTU |
| Boiler for hot water heat |
75,000 - 200,000 BTU |
| Unvented space heater |
30,000 BTU |
| Gas logs |
45,000 BTU |
| Suspended unit heater, for garage |
25,000 – 100,000 BTU |
| Swimming pool heater |
250,000 BTU |
| Spa heater |
80,000 BTU |
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Why is pipe size important?
When vapor flows through pipe or tubing a measurable amount of friction slows the flow. If the flow is slowed too greatly, the resultant drop in pressure may cause the appliance being supplied to burn improperly. This can create unnecessary service calls and appliance failure. The relative friction of a small pipe is greater than that of a larger pipe. Therefore, if the pipe is undersized, the full operating pressure of the appliance will not make it to the appliance.
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What is the Material Safety Data for propane?
MATERIAL SAFETY DATA SHEET For Odorized Propane
Product Name: Odorized Commercial Propane
Chemical Name: Propane
Chemical Family: Paraffinic Hydrocarbon
Chemical Formula: C3H8
Synonyms: Dimethylmethane, LP-Gas, Liquefied Petroleum Gas (LPG), Propane, Propyl Hydride
Shelby Bottled Gas Corp.
1340 N. Michigan Road
PO Box 508
Shelbyville, IN 46176-0508 |
Transportation
Emergency Number 1-800-535-5053
Emergency Number: 1-800-574-3529
For routine information: 1-800-845-4434 |
Composition/Information
On Ingredients
| INGREDIENT NAME |
PERCENTAGE |
OSHA PEL |
ACGIH TLV |
| /CAS Number |
|
|
|
| Propane/74-98-6 |
87.5-100 |
1000 ppm |
Simple asphyxiant |
| Ethane/74-84-0 |
0-5.0 |
1000 ppm |
Simple asphyxiant |
| Propylene/115-07-1 |
–10.0 |
1000 ppm |
Simple asphyxiant |
| Butanes/various |
0-2.5 |
1000 ppm |
Simple asphyxiant |
| Ethyl Mercaptan/75-08-1 |
16-25ppm |
0.5 ppm |
0.5 ppm |
Hazards Identification
Emergency Overview
DANGER! Flammable liquefied gas under pressure. Keep away from heat, sparks, flame, and all other ignition sources. Vapor replaces oxygen available for breathing and may cause suffocation in confined spaces. Use only with adequate ventilation. Odor may not provide adequate warning of potentially hazardous concentrations. Vapor is heavier than air. Liquid can cause freeze burn similar to frostbite. Do not get liquid in eyes, on skin, or on clothing. Avoid breathing of vapor. Keep container valve closed when not in use.
POTENTIAL HEALTH
EFFECTS INFORMATION
ROUTES OF EXPOSURE:
Inhalation: Asphyxiant. It should be noted that before suffocation could occur, the lower flammability limit of propane in air would be exceeded, possibly causing both an oxygen-deficient and explosive atmosphere. Exposure to concentrations >10% may cause dizziness. Exposure to atmospheres containing 8%-10% or less oxygen will bring about unconsciousness without warning, and so quickly that the individuals cannot help or protect themselves. Lack of sufficient oxygen may cause serious injury or death.
Eye Contact: Contactwith liquid can cause freezing of tissue.
Skin Contact: Contact with liquid can cause frostbite.
[Skin Absorption]: None.
[Ingestion]: Liquid causes freeze burn similar to frostbite. Ingestion not expected to occur in normal use.
CHRONIC EFFECTS: None.
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: None.
OTHER EFFECTS OF OVEREXPOSURE: None.
CARCINOGENICITY: NTP, OSHA, or IARC does not list Propane.
First Aid Measures
INHALATIONS: Persons suffering from lack of oxygen should be removed to fresh air. If victim is
not breathing, administer artificial respiration. If breathing is difficult, administer oxygen. Obtain prompt medical attention.
EYE CONTACT: Contact with liquid can cause freezing of tissue. Gently flush eyes with lukewarm water. Obtain medical attention immediately.
SKIN CONTACT: Contact with liquid can cause frostbite. Remove saturated clothes, shoes and jewelry. Immerse affected area in lukewarm water not exceeding 105 F. Keep immersed. Get prompt medical attention.
IGESTION: If swallowed, get immediate medical attention.
NOTES TO PHYSICIAN: None.
FLASH POINT: -156 F (-104 C) AUTOIGNITION: 842 F (432 C)
IGNITION TEMPERATURE IN AIR: 920-1120 F
FLAMMABLE LIMITS IN AIR BY VOLUME: Lower: 2.15% Upper: 9.6%
EXTINGUISHING MEDIA: Dry chemical, CO2, water spray or fog for surrounding area. Do not extinguish fire until propane source is shut off.
SPECIAL FIRE-FIGHTING INSTRUCTIONS: Evacuate personnel from danger area. Immediately cool container with water spray from maximum distance, taking care not to extinguish flames. If flames are accidentally extinguished, explosive re-ignition may occur. Where water is abundant and immediate, the fire should be allowed to burn while
the container and area are cooled and the flow of propane is shut off. Where water is scarce, compare the risk of allowing the area to continue to heat
from the fire and the alternative of extinguishing the fire without shutting off the propane flow, which may allow for the propane to
accumulate and re-ignite explosively. UNUSUAL FIRE AND
EXPLOSION HAZARDS: Propane is easily ignited. It is heavier than air; therefore, it can collect in low areas where an ignition source can be present. Pressure in a container can build up due to heat and container
may rupture if pressure relief devices should fail to function. Propane released from a properly functioning relief valve on
an overheated container can also become ignited.
HAZARDOUS COMBUSTION PRODUCTS: None.
Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Evacuate the immediate area. Eliminate any possible sources of ignition and provide maximum
ventilation. Shut off source of propane, if possible. If leaking from container, or valve, contact your supplier.
Handling And Storage
HANDLING PRE-CAUTIONS: Propane vapor is heavier than air and can collect in low areas that are without sufficient ventilation. Leak-check system with a leak detector or solution, never with flame. Make certain the container service valve is shut off prior to connecting or disconnecting. If container valve does not operate properly, discontinue use and contact supplier. Never insert an object (e.g. wrench, screwdriver, pry bar, etc.) into pressure relief valve or cylinder valve cap openings. Do not drop or abuse cylinders. Never strike an arc on a gas container or make a container part of an electrical circuit. See ``OTHER INFORMATION’’ for additional precautions.
STORAGE PRECAUTIONS: Store in a safe, authorized location (outside, detached storage is preferred) with adequate ventilation. Specific requirements are listed in NFPA 58, Standard for the Storage and Handling of Liquefied Petroleum
Gases. Isolate from heat and ignition sources. Containers should never be allowed to reach temperature exceeding 125 F (52 C). Isolate from combustible materials. Provide separate storage locations for other compressed and flammable gases. Propane containers should be separated from oxygen cylinders, or other oxidizers, by a minimum distance of 20 feet, or by a barrier of non-combustible material at least 5 feet high having a fire rating of at least ½ hour. Full and empty cylinders should be segregated. Store cylinders in upright position, or with pressure relief valve in vapor space. Do not drop or abuse cylinders. Keep container valve closed and plugged or capped when not in use. Install protective caps when cylinders are not connected for use. Empty containers retain some residue and should be treated as if they were full.
Exposure Controls/Personal Protection
ENGINEERING CONTROLS
Ventilation: Provide ventilation adequate to ensure propane does not reach a flammable mixture.
RESPIRATORY PROTECTION (SPECIFY TYPE)
General Use: None.
Emergency Use: If concentrations are high enough to warrant supplied-air or self-contained breathing apparatus, then the atmosphere may be flammable
(See Fire-Fighting
Measures). Appropriate precautions must be taken regarding flammability.
PROTECTIVE CLOTHING: Avoid skin contact with liquid propane because of possibility of freeze burn. Wear gloves and protective clothing, which are impervious to the product for the duration of the anticipated exposure.
EYE PROTECTION: Safety glasses are recommended when handling cylinders.
OTHER PROTECTIVE EQUIPMENT: Safety shoes are recommended when handling cylinders.
Physical and Chemical Properties
BOILING POINT: @ 14.7 psia = -44 F
SPECIFIC GRAVITY OF
VAPOR: (Air = 1) at 60 F: 1.50
SPECIFIC GRAVITY OF LIQUID: (Water = 1) at 60 F: 0.504
VAPOR PRESSURE: @ 70 F = 127 psig 105 F = 210 psig
EXPANSION RATIO (From liquid to gas @ 14.7 psia): 1 to 270
SOLUBILITY IN WATER: Slight, 0.1 to 1.0%
APPEARANCE AND ODOR: A colorless
and tasteless gas at normal temperature and pressure. An odorant (ethyl mercaptan) has been added to provide a
strong unpleasant odor. Should a propane-air mixture reach the lower limits of flammability, the ethyl mercaptan concentration will be approximately 0.5 ppm in air.
ODORANT WARNING: Odorant is added to aid in the detection of leaks. One common odorant is ethyl mercaptan, CAS No. 75-08-01. Odorant has a foul smell. The ability of people to detect odors varies widely. Also, certain chemical reactions with material in the propane system, or fugitive propane gas from underground leaks passing
through certain soils, can reduce the odor level. No odorant will be 100% effective in all circumstances. If odorant appears to be weak, notify propane supplier immediately.
Stability and Reactivity
STABILITY: Stable. Conditions to Avoid: Keep away from high heat, strong oxidizing agents and sources of ignition.
REACTIVITY: Hazardous Decomposition Products: Under fire conditions, fumes, smoke, carbon monoxide, aldehydes and other decomposition products. When used as an engine fuel, incomplete combustion can cause carbon monoxide, a toxic gas.
Hazardous polymerization: Will not occur.
Toxicological Information
Propane is non-toxic and is a simple asphyxiant, however, it does have slight anesthetic properties and higher concentrations may cause dizziness.
[IRRITANCY OF MATERIAL]: None
[SENSITIZATION TO MATERIALS]: None.
[REPRODUCTIVE
EFFECTS]: None.
[TERATOGENICITY]: None
[MUTAGENICITY]: None.
[SYNERGISTIC
MATERIALS]: None
Ecological Information
No adverse ecological effects are expected. Propane does not contain any Class I or Class II ozone-depleting chemicals (40 CFR Part 82). Propane is not listed as a marine pollutant by DOT (49 CFR Part 171).
Disposal Considerations
WASTE DISPOSAL METHOD: Do not attempt to dispose of residual or unused product in the container. Return to supplier for safe disposal.
Residual product
within process system may be burned at a controlled rate, if a
suitable burning unit (flare stack) is available on site. This shall be done in accordance with federal, state and local
regulations.
Transport Information
DOT SHIPPING NAME: Liquefied Petroleum Gas
HAZARD CLASS: 2.1 (Flammable Gas) IDENTIFICATION NUMBER: UN 1075
PRODUCT RQ: None. SHIPPING LABEL(S): Flammable Gas
IMO SHIPPING NAME: Propane
PLACARD (WHEN REQUIRED): Flammable Gas
IMO IDENTIFICATION
NUMBER: UN 1978
SPECIAL SHIPPING INFORMATION: Container should be transported in a secure, upright position in a well-ventilated vehicle.
Regulatory Information
The following information concerns selected regulatory requirements potentially applicable to this product. Not all such requirements are identified. Users of this product are responsible for their own regulatory compliance on a federal, state [provincial] and local level.
U.S. FEDERAL REGULATIONS
EPA Environment Protection Agency
| CERCLA |
Comprehensive Environmental Response, Compensation & Liability Act of 1980 (40 CFR Parts 117 and 302)
Reportable Quantity (RQ): None. |
| SARA |
Superfund Amendment and Reauthorization Act
SECTION 302/304: Requires emergency planning on threshold planning quantities (TPQ) and release reporting based on reportable quantities (RQ) of EPA’S extremely hazardous substances (40 CFR Part 355).
Extremely Hazardous Substances: None
Threshold Planning Quantity (TPQ): None
SECTIONS 311/312: Require submission of material safety data sheets (MSDSs) and chemical inventory reporting with identification of EPA-defined hazard classes (40 CFR Part 370). The hazard classes for this product are:
|
|
IMMEDIATE: No DELAYED: No |
PRESSURE: Yes REACTIVITY: No |
FLAMMABLE: Yes |
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SECTION 313: Requires submission of annual reports of release of toxic chemicals that appear in 40 CFR Part 372.
Propane does not require reporting under Section 313.
40 CFR PART 68 Risk Management for Chemical Accidental Release
TSCA Toxic Substance Control Act
Propane is listed on the TSCA inventory
OSHA Occupational Safety and Health Administration
29 CFR 1910.119: Process Safety Management of Highly Hazardous Chemicals.
FDA Food and Drug Administration
21 CFR 184.1655: Generally recognized as safe (GRAS) as a direct human food when used as a propellant, aerating agent and gas. |
Other Information
SPECIAL PRECAUTIONS: Use piping and equipment adequately designed to with stand pressure to be encountered.
NFPA 58 Standard for the Storage and Handling of Liquefied Petroleum Gases and OSHA 29 CFR 1910.10 require that all persons employed in handling LP-gases be trained in proper handling and operating procedures, which the employer shall document. Contact your propane supplier to arrange for the required training. Allow only trained and qualified persons to install and service propane containers and systems.
WARNING: Be aware that with odorized propane the intensity of ethyl mercaptan stench (its odor) may fade due to chemical oxidation (in the presence of rust, air or moisture), adsorption or absorption. Some people have nasal perception problems and may not be able to smell the ethyl mercaptan stench. Leaking propane from underground gas lines may lose its odor as it passes through certain soils. While ethyl mercaptan may not impart the warning of the presence of propane in every instance, it is generally effective in a majority of situations. Familiarize yourself, your employees and customers with this warning, and other facts associated with the so-called ``odor-fade’’ phenomenon.If you do not already know all the facts, contact your propane supplier for more information about odor, electronic gas alarms and other safety considerations associated with the handling, storage and use of propane.
ISSUE INFORMATION
Issue Date: January 2000
This material safety data sheet and the information it contains is offered to you in good faith as accurate. This Supplier does not manufacture this product but is a supplier of the product independently manufactured by others. Much of the information contained in this data sheet was received from sources outside our Company. To the best of our knowledge this information is accurate, but this Supplier does not guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user’s obligation to evaluate and use this product safely, comply with all applicable laws and regulations, and to assume the risks involved in the use of this product.
NO WARRANTY OR MERCHANTABILTIY, FITNESS FOR ANY PARTICULAR PURPOSES, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF COMPLETENESS OF THIS INFORMATION, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE.
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